Selenium Stabilized Carbenium Ions on Organic Synthesis
نویسندگان
چکیده
منابع مشابه
Selenium Stabilized Carbenium Ions on Organic Synthesis
Organoselenium compounds have been known for a long time as versatile reagents in organic chemistry. In the last years there has been a considerable development of selenium-based methods for organic synthesis. Many of these methods are currrently been used as standard procedures to introduce new functional groups under mild conditions. From the several areas of interest in organoselenium chemis...
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Recent results in the chemistry of disubstituted carbenium ions (vinyl cations and phenyl cations) are described separately under three different sections: From kinetic and solvolytic data of several 1—cyclobutenyl nonaflates, the intermediacy of a non-classical vinyl cation, namely the 1-cyclobutenyl cation 2 is established. Cycloaddition reactions of solvolytically generated vinyl cations wit...
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Diphenyl-, aryl-a-siloxyand %-furany1 carbenes can be protonated by even weak proton donors such as alcohols (by a bimolecular or by a pre-association mechanism involving more than one alcohol molecule) to yield the corresponding carbenium ions, whose spectra and electrophilic patterns of behavior are described. INTRODUCTION Proton transfer reactions to and from heteroatoms (= "normal" Bronsted...
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A ferramenta de Gassman-Fentiman da demanda crescente de elétrons foi usada para identificar íons carbênios e íons carbônios. Contudo, devido ao seu entendimento ambíguo, ela foi pivô de uma disputa histórica. Nós aplicamos a metodologia da Teoria Quântica de Átomos em Moléculas QTAIM para caracterizar íons carbênios e íons carbônios de uma forma mais eficaz e mais fácil. Essa metodologia pode ...
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Attachment of a transition metal moiety to an olefinic ligand presents the organic chemist with unequaled opportunities to control the regio- and stereospecificities of bond formation. Applications of cationic dienyliron-carbonyl complexes to a range of natural product syntheses have been developed. These applications show how the iron-carbonyl unit directs the regio- and stereochemistry of nuc...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 1998
ISSN: 0103-5053
DOI: 10.1590/s0103-50531998000400005